为了促进从化石到可再生能源的转移,需要存储以应对太阳,风能和波浪功率等技术的间歇性质。一种存储替代方案是基于电池的固定能量存储。有许多电池类型可供选择,但是镍金属氢化物(NIMH)是特别适合的类型。这些电池具有高的能量密度,一个较大的温度操作窗口,是大规模存储的安全替代方案。在本文中,研究了NIMH电池的行为,目的是开发动态电池模型,该模型能够复制电池电压和压力,也用于动态使用。这种模型可用于促进NIMH电池的开发,改进电池管理系统(BMS)中使用的算法,质量控制以及储能系统的尺寸。这些改进可以导致固定的能量存储,并具有更高的效率和更长的可用寿命。为了提高对电池功能的理解,对NIMH电池典型的两种行为进行了更深入的研究,并被认为对电池有很大的影响:开路电压(OCV)磁滞和电池气体相的行为。OCV磁滞会使建模复杂化,因为它会导致电池休息电压在一定程度上取决于到达那里所需的充电/排放路径。OCV磁滞对于所有电池都不明显,对于NIMH电池来说尤其突出。然后将氧气在负电极处重新组合到水中。NIMH电池中的气相是有效的,因为电解质是水性的,并且在操作过程中的电压窗口会导致正电极处的氧气演化。由于对负金属氢化物电极上氢平衡压力的依赖性和氢平衡压力的依赖性,气相中的氢量在周期内有所不同。分别开发了两个模型以研究这些行为。模型显示出良好的定性生殖能力。还使用结构分析方法研究了磁滞现象。在相同的电荷状态下的两个阳性电极材料样品之间的材料结构中发现了差异,但滞后状态不同。这些差异是
基于机器学习(ML)型号和现实世界中收集的锂离子电池(LIB)数据的电池性能预测技术最近受到了很多关注。但是,对于使用现实世界数据的ML模型来说,较差的外推精度是一个主要挑战,因为数据频率分布可能不均匀。在这里,我们使用电化学模拟模型生成的人工数据研究了ML模型的外推精度。特别是,我们为训练数据设置了较低的开路电压(OCV)限制,并生成数据限于较高的充电状态(SOC)区域,以训练电压预测模型。我们已经验证了在几个较低的OCV限制设置下测试数据的电压的均方根误差(RMSE),并将其平均 + 3标准偏差定义为评估度量。评估了八种代表性的ML模型,发现多层感知器(MLP)的精度为92.7 mV,这是最佳的外推精度。我们还评估了具有已发布的实验数据的模型,发现MLP的精度为102.4 mV,重新确定其具有最佳的外推精度。我们还发现,MLP对感兴趣数据的变化具有鲁棒性,因为从模拟到实验数据变化时的准确性降解为1.1。此结果表明,即使为全面的SOC条件收集数据很困难,MLP也可以实现更高的电压预测准确性。
图3-11:MATLAB SIMULINK模拟设计的电池。 .................... 40 Figure 3-12 MATLAB SIMULINK simulation of battery comparison. ................. 41 Figure 3-13: SOC results of comparison simulation................................................ 42 Figure 3-14: OCV results of first order RC batteries comparison. ...............................................................................................................................................................................................................................................................................................................................................................................................二阶RC电池比较的OCV结果。 ..................... 43 Figure 4-1 Traditional bridge-type PWM inverter. (a)拓扑。 (b)波形[30]。 .......................................................................................................................... 45 Figure 4-2 LC Filter equivalent circuit. ................................................................... 46 Figure 4-3: The V2L electrical circuit. .................................................................... 49 Figure 4-4: The equivalent circuit of the V2L system. ............................................ 49 Figure 4-5 Bode Plot of the voltage plant. ............................................................... 52 Figure 4-6: Bode Plot of the current plant. .............................................................. 53 Figure 4-7 the block diagram of the outer voltage control loop with the inner current loop. .......................................................................................................................... 54 Figure 4-8: MATLAB SIMULINK simulation of complete system. .................................................... 57 Figure 4-11 Inductor current result of the system. 。图3-11:MATLAB SIMULINK模拟设计的电池。.................... 40 Figure 3-12 MATLAB SIMULINK simulation of battery comparison.................. 41 Figure 3-13: SOC results of comparison simulation................................................ 42 Figure 3-14: OCV results of first order RC batteries comparison................................................................................................................................................................................................................................................................................................................................................................................................二阶RC电池比较的OCV结果。 ..................... 43 Figure 4-1 Traditional bridge-type PWM inverter. (a)拓扑。 (b)波形[30]。 .......................................................................................................................... 45 Figure 4-2 LC Filter equivalent circuit. ................................................................... 46 Figure 4-3: The V2L electrical circuit. .................................................................... 49 Figure 4-4: The equivalent circuit of the V2L system. ............................................ 49 Figure 4-5 Bode Plot of the voltage plant. ............................................................... 52 Figure 4-6: Bode Plot of the current plant. .............................................................. 53 Figure 4-7 the block diagram of the outer voltage control loop with the inner current loop. .......................................................................................................................... 54 Figure 4-8: MATLAB SIMULINK simulation of complete system. .................................................... 57 Figure 4-11 Inductor current result of the system. 。...............................................................................................................................................................................................................................................................................................................................................................................................二阶RC电池比较的OCV结果。..................... 43 Figure 4-1 Traditional bridge-type PWM inverter.(a)拓扑。(b)波形[30]。.......................................................................................................................... 45 Figure 4-2 LC Filter equivalent circuit.................................................................... 46 Figure 4-3: The V2L electrical circuit..................................................................... 49 Figure 4-4: The equivalent circuit of the V2L system............................................. 49 Figure 4-5 Bode Plot of the voltage plant................................................................ 52 Figure 4-6: Bode Plot of the current plant............................................................... 53 Figure 4-7 the block diagram of the outer voltage control loop with the inner current loop........................................................................................................................... 54 Figure 4-8: MATLAB SIMULINK simulation of complete system..................................................... 57 Figure 4-11 Inductor current result of the system.。...................... 55 Figure 4-9: Output voltage result of the system....................................................... 56 Figure 4-10: Output current result of the system.................................................... 57 Figure 4-12: PWM Waveforms of the system.............................................................................................................................................................................................................................................................................................................................................................................................................................................................................. 58图4-14输出和参考电压....................................................................................................................................... 60 Figure 5-2: Experimental Setup............................................................................... 61 Figure 5-3: Experimental setup; (1)variac,(2)3-φ整流器,(3)控制器,(4)电阻载荷,(5)逆变器,(6)DSP板和电平换挡器电路,(7)示波器,(8)LC滤波器。..................................................................................... 61 Figure 5-4: The connection diagram of the F28335 processor and the level shifter................................................................................................................................... 63 Figure 5-5: Experimental Setup Connection of DSP board and the Level Shifter.64图5-6:无过滤器的逆变器的输出电压。...................................... 65 Figure 5-7: Load voltage and current....................................................................... 66 Figure 5-8: Load Voltage.............................................................................................................................................................................. 71........................................................................................ 66 Figure 5-9 Transient Current and Voltage of Kettle ................................................ 67 Figure 5-10 Transient Current and Voltage of Microwave ..................................... 67 Figure 5-11 Steady-State Current and Voltage of Kettle ......................................... 68 Figure 5-12 Steady-State Current and Voltage of Microwave ................................ 68 Figure 6-1 CHAdeMO Connector and Pin Layout [45].
Figure 1-1 Evolution of electromobility [1] .................................................................................... 3 Figure 1-2 Schematic diagram of a Li-ion battery and main reactions [2] .................................... 4 Figure 1-3 Schematic diagram of a PHEV pack manusfactured by A123 Sysems .......................... 6 Figure 2-1 Single particle model (on the right) based on沿X轴完全电化学模型的空间离散化(左侧)。每个电极只有一个粒子,我们可以将每个节点的值视为电极上的平均数量[22]。............ 13 Figure 2-2 Different types of battery models used in battery management systems (Single particle and Pseudo-two dimensional models from [24]) ........................................................................... 15 Figure 2-3 Concentration gradient through the sphere, representing the single particle model .16图2-4 G(S)及其近似H(S)的比较。........................................................ 16 Figure 2-5 Comparison of fractional transfer function and its approximation in a frequency domain limited to the range including the BMS sampling frequency (approx.70 rad.s -1)。........... 18 Figure 2-6 Block diagram implementation of the electrical fractional model .............................. 18 Figure 2-7 OCP curves of Anode (left) and Cathode (right) against the respective lithiation degree ............................................................................................................................................. 21 Figure 2-8 Validation results of applying extended Artemis drive cycle to the fractional 模型 。23图2-9电压模型和分数电池模型的绝对估计误差和订单7 ECM的各自的绝对估计误差。................................................................................................................................................ 48 Figure 4-6 SDI 28 Ah cell opening at BOL ................................................................................... 52 Figure 4-7 SDI 28 Ah cell opening at EOL ................................................................................... 52
正在维护环境参数(即温度、湿度、水质等)。2. 每个陆生动物房间都应放置最小/最大温度计和湿度计,并每天记录温度和湿度读数。有关特定物种的环境参数要求,请参阅指南、AWA 或农业指南,或联系 OCV。3. 对于啮齿动物,研究人员应注意低相对湿度和缓解措施的影响。有关更多信息,请参阅 WSU IACUC SOP #12。4. 根据需要至少每 3 年测量一次室内住房区域的通风率。水生物种住房通常不包括在监测范围内5. 饲养在谷仓、牧场和其他室外住房位置的牲畜和野生动物不需要记录环境监测,但必须按照农业指南提供足够的通风和住房。
这项研究介绍了𝛥𝑄 -method,该方法依赖于放松的电压点和这些点之间的累积电荷。它独立于当前利率,几乎在每个事件之后都适用。优化问题最小化了测量和重建𝛥𝑄之间的偏差。该方法是使用汽车单元格数据集开发的,并使用BMW i3的现实世界数据进行验证。the -method达到了2的平均绝对SOH估计误差2。52%和平均绝对OCV重建误差为7。19 mv。可靠的估计由预定义的过滤器确保。该方法在限制的电荷状态(SOC)窗口或有限的数据点中保持有效。它与输入数据,求解器选择和优化设置的变化相对可靠。通过约束解决方案空间来改善收敛性。
摘要膜电极组件(MEA)的性能阻碍了燃料电池的商业化。MEA受加湿,温度和氢气流量的极大影响。在这项研究中,使用PT/C和COFE/N-C催化剂在质子交换膜燃料电池中确定工作条件对MEA的影响。在此,制备了两种使用NAFION-212膜的MEAS类型的测量和测试。第一个MEA的阳极和阴极分别用Pt/C和COFE/N-C催化剂覆盖,而第二个MEA在两个电极上使用了PT/C催化剂。使用循环伏安法和电化学障碍光谱谱分别以PT/C和COFE/N-C催化剂的形式表征了电极,分别获得电化学表面积(ECSA)和电导率的电导率。在不同的工作条件下测试了两个测量的性能,例如各种加湿器温度(40°C,60°C,80°C和100°C)和氢气流速(100、200、300和400 mL/min)。具有PT /C催化剂的电极比COFE /N-C电极(0.018 m 2 /g)表现出更高的ECSA(0.245 m 2 /g)。类似地,PT/C电极具有比COFE/N-C电极(4.4×10 -3 s/cm)更高的电导率(7.2×10 -3 s/cm)。因此,在两个电极上使用PT/C催化剂的第二MEA的开路电压(OCV)均显示出比第一MEA(0.790 V)的OCV更高的值(0.890 V)。此外,加湿器温度在80°C下最佳,并且在第二个和第一个MEA中,其功率密度水平分别高达10.14和3.43 mW/cm 2。此外,MEA的性能还受氢气流量的影响。在第一个MEA的最佳氢气流速为400 mL/min的情况下,实现了4.93 mW/cm 2的功率密度。同时,第二个MEA需要较低的氢气流速(200 mL/min)才能达到10.14 mW/cm 2的最大功率密度。关键字:质子交换膜燃料电池,MEA性能,Co-Fe/n-C,加湿温度,氢气流速
摘要——基于锂离子 (Li-ion) 电池的电池组被广泛用于许多应用中。电池管理系统 (BMS) 是根据特定输入描述电池的状态,以获得可用于系统控制的多个输出。本文介绍了 DC/DC 降压转换器在锂离子电池充电中的应用和控制。可以估计描述电池充电容量状态的主要参数是充电状态 (SoC)。SoC 是根据电池开路电压 (OCV) 和库仑计数法估计的。控制 SoC 限值以避免电池过度充电。脉冲调整 (PA) 控制技术用于控制用于给锂离子电池充电的 DC/DC 降压转换器的开关。因此,在充电过程开始时,确保充电电流在允许的限度内恒定。因此避免过热,这可能会降低或损坏电池。MATLAB/Simulink 工具用于设计验证。模拟和实际结果令人鼓舞。移动应用程序旨在监控电池充电/放电参数。
该角色通常由电池管理系统(BMS)提供,该系统利用简单的电流,电压和脾气测量值来监视SOC和SOH在包装或模块级别上。流行的EV模型利用细胞组织为由中央BMS控制的模块。例如,特斯拉模型S包含7140×18 650个细胞(在16个平行和6个串联细胞的16个模块中),2个和2个串联电池,以及BMS MONI-MONI-MONI-MONI-MONI-MONI-MONI-MON-MONI-MON-MON-TOUCTION电池电压和温度,并防止过电压。3日产叶包含一个30 kW h电池组,该电池组由192个小袋单元组成,该小袋单元在8细胞模块,4和通过开路电压(OCV)和电荷计数(CC)方法组成。5此模块化BMS设计的可用数据范围有限,因此显示的范围值充其量是一个粗略的估计值。此外,模块级方法意味着它无法响应单个单元失败