最近,由于新的量子混合系统的出现,人们已经有了新的兴趣和实验研究,用于在固体中进行旋转,这需要操纵自旋量子状态1-3,并继续搜索可行的候选者2,4。在这项工作中,我们介绍了低语画廊(WG)模式技术,以研究杂质的顺磁性离子不成对的电子自旋共振,在Di-Electric Crystal Grattice 5-7中具有核超精美偶联。Srlaalo 4(SLA)sin- Gle晶体晶格中杂质顺磁离子的位点对称信息是通过WG多模式ESR光谱获得的(图1、2、3和4),提供了超精细结构拓宽,g因素变量和其他各向异性效应的微妙效果。wg模式光谱具有高度敏感的,与实验结果的多模式性质相结合,提供了某些具有高精度的基本物理量的值。金属配体八面体配合物中的jahn-teller效应通常会诱导电荷耦合,轨道和磁有序,位移,并在确定电子行为8-11时强调结构细节。高精细结构特征的这种高精度调查对于量子状态映射至关重要。未配对的电动旋转力矩揭示了有关旋转的信息 -
1。INORGANIC CHEMISTRY: Group theory: The concept of group, Symmetry elements and symmetry operations, Assignment of point groups toInorganic molecules, some general rules for multiplications of symmetry operations, Multiplication tables for water andammonia, Representations (matrices, matrix representations for C 2 V and C 3 V point groups irreducible representations), Character and character tables for C 2 V and C 3 V point groups.群体理论在化学键合中的应用(在不同几何和π键的杂交轨道和杂种轨道中的杂交轨道。BF 3,C 2 H 4和B 2 H 6中的分子轨道对称性,非水溶剂:证明需要非水溶性溶液化学和水作为溶剂失败的因素。硫酸的溶液化学:物理特性,H 2 SO 4中的离子自脱水,具有高粘度的高电导性,H 2 SO 4的化学性能为酸,作为脱水剂,作为氧化剂,作为氧化剂,作为一种培养基酸碱中和中和含量分化的溶剂。液体BRF 3:物理特性,BRF 3中的溶解度,自我离子,酸基碱中和反应,溶解反应和过渡金属氟化物的形成,无机氢化物:分类,制备,粘结及其应用。过渡金属化合物邦德斯托氢,羰基氢化物和氢化物阴离子。Tanabe Sugano图,Orgeldiagrams,B,C和β参数的评估。分类,命名法,韦德的规则,制备,结构和结合(硼烷)(硼烷)和碳纤维,螯合物,决定螯合物稳定性的因素(环大小,主题的氧化状态,主题的氧化状态,主题的均值,主题的均值); Organic Reagents in Inorganic Chemistry: Use of the following reagents in analysis: Dimethylglyoxime (in analytical chemistry), EDTA (in analytical chemistry and chemotherapy), 8-Hydroxyquinoline (in analytical chemistry and chemotherapy), 1, 10-Phenanthroline (in analytical chemistry and chemotherapy), Thiosemicarbazones (in analytical chemistry and chemotherapy),二乙烷(在分析化学和化学疗法中)。Metal-Ligand Bonding-I: Recapitulation of Crystal Field Theory including splitting of d -orbitals in different environments, Factors affecting the magnitude of crystal field splitting, structural effects (ionic radii, Jahn-Teller effect),Thermodynamic effects of crystal field theory (ligation, hydration and lattice energy), Limitations of crystal field theory, Adjusted Crystal Field Theory (ACFT), Evidences for Metal-Ligand在复合物中重叠,分子轨道理论是conthe骨,四面体和方形平面复合物(不包括数学处理)。磁化学:磁矩的起源,磁敏感性(磁磁性,顺磁性),仅旋转力矩,罗素·萨德(Russell SaunderAtomic Spectroscopy: Energy levels in an atom, coupling of orbital angular momenta, coupling of spin angular momenta, spin orbit coupling, spin orbit coupling p2 case, Determining the Ground State Terms-Hund's Rule, Hole formulation (derivation of the Term Symbol for a closed sub-shell, derivation of the terms for a d2 configuration), Calculation of the number of themicrostates, Electronic Spectra-I: Splitting of spectroscopic terms (S,P,D.F and G,H,I), d 1 -d 9 systems in weak fields (excluding mathematics), strong field configurations, transitions from weak to strong crystalfields, Electronic Spectra-II: Correlation diagrams (d 1 -d 9 ) in OhandTd environments, spin-crossoverin coordination compounds.