高能密度锂金属电池是首选的下一代电池系统,并用聚合物固态电解质代替易燃液体电解质是实现高安全性和高特异性设备的重要性。不幸的是,电极/电解质和Li树突生长之间的固体 - 固体接触较差的固有的棘手问题阻碍了其实际应用。The in-situ solidification has demonstrated a variety of advantages in the application of polymer electrolytes and artificial interphase, including the design of integrated polymer electrolytes and asymmetric polymer electrolytes to enhance the compatibility of solid–solid contact and compatibility between various electrolytes, and the construction of artificial interphase between the Li anode and cathode to suppress the formation of Li dendrites and to增强聚合物电解质的高压稳定性。本综述首先阐述了固态电池的原位固化历史,然后专注于固化电解质的合成方法。此外,总结了聚合物电解质的设计和人工之间的构建,原地固化技术的最新进展也得到了总结,并且强调了原位固化技术在增强安全性方面的重要性。最后,设想了前景,新兴挑战和实用固化的实际应用。
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